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You can try choosing Tools > Options > OpenOffice.org Writer > Mail Merge Email and specify the correct email settings in that window. The email settings will depend on your email setup. You can also go into the Windows control panel and find the icon for Internet. Then, in the window that that icon opens, look for a tab that says Programs or Default Programs. Select your email program as your default email program, and click OK.
Regarding the templates, this depends on your operating system. On my Windows computer, templates are stored in an Application Data directory outside of any OpenOffice.org directory, so you'll be able to access them from each new installation in the same way. Or just copy all your templates to a directory like C:myopenofficetemplates. Then, under Tools > Options > OpenOffice.org > Paths, Template item, just point to your template directory each time you install a new version.
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